Temperature-jump induced cation exchange kinetics in (Co<Subscript>0.1</Subscript>Mg<Subscript>0.9</Subscript>)<Subscript>2</Subscript>SiO<Subscript>4</Subscript> olivine: an in situ optical spectroscopic study     

Jianmin Shi  Stefan G. Ebbinghaus  Klaus Dieter Becker 《Physics and Chemistry of Minerals》2008,35(1):1-9

In the olivine crystal structure, cations are distributed over two inequivalent octahedral sites, M1 and M2. Kinetics of cation exchange between the two octahedral sites in (Co_0.1Mg_0.9)₂SiO₄ single crystal have been studied in the temperature range from 600 to 800°C by monitoring the time evolution of the absorbance of Co²⁺ ions in M1 or M2 sites using optical spectroscopy after rapid temperature jumps. It was found from such temperature-jump induced relaxation experiments that with increasing temperature the absorbance of Co²⁺ ions in the M1 site decreases while that in the M2 site increases. This indicates a tendency of Co²⁺ cations to populate the M2 site with increasing temperatures and vice versa. The experimental relaxation data can be modeled using a triple exponential equation based on theoretical analysis. Activation energies of 221 ± 4 and 213 ± 10 kJ/mol were derived from relaxation experiments on the M2 site and M1 site, respectively, for the cation exchange processes in (Co_0.1Mg_0.9)₂SiO₄ olivine. Implications for cation diffusion at low temperatures are discussed.  相似文献   

Cadmium stable isotope cosmochemistry   总被引：2，自引：0，他引：2  

Frank Wombacher  Mark Rehkämper  Klaus Mezger  Carsten Münker 《Geochimica et cosmochimica acta》2008,72(2):646-667

Cadmium stable isotope compositions are reported for a comprehensive suite of carbonaceous, ordinary, enstatite, and Rumuruti chondrites as well as achondrites and lunar samples (soils, breccias, pristine anorthosite). The Cd isotope analyses were performed by multiple collector ICP-MS with an external reproducibility of ±0.43‰ (2 sd) for δ^114/110Cd. None of the samples shows evidence of nucleosynthetic anomalies and cosmogenic isotope effects from neutron-capture by ¹¹³Cd were only observed for two lunar samples.The Cd stable isotope compositions of type 1, 2, and some type 3 carbonaceous chondrites, EH4 enstatite chondrites, eucrites, and the Earth are essentially identical at δ^114/110Cd ≈ 0.0 ± 0.4. This suggests that the portion of the solar nebula from which the inner solar system bodies accreted was homogeneous with respect to its Cd isotope composition. It also indicates that the primary volatile element depletion of the inner solar system did not involve partial kinetic Rayleigh evaporation or condensation. Furthermore no resolvable Cd isotope effects were generated during the accretion and initial differentiation of the planetary bodies.In contrast, the analyses reveal large Cd isotope effects for ordinary and some enstatite chondrites, which display δ^114/110Cd values between about −8 and +16. Smaller fractionations are observed for the Rumuruti and some type 3 to 5 carbonaceous chondrites. These Cd isotope variations are thought to reflect secondary depletion or redistribution of Cd, due to open system thermal metamorphism on the meteorite parent bodies.One CAI and chondrule separates from the Allende meteorite have unexpectedly high Cd concentrations and fractionated light Cd isotope compositions with δ^114/110Cd ≈ −1 to −4. These characteristics may have been established by the interaction of originally Cd-poor materials with a volatile-rich gas prior to the final accretion of the Allende parent body. The general Cd enrichment of the lunar soil and regolith mainly reflects early volcanic activity. However, decreasing Cd abundances in lunar soils correlate well with an enrichment of the heavy Cd isotopes. This relationship is best explained by suppressed Rayleigh fractionation in response to space weathering.  相似文献   

The Rila-Pastra Normal Fault and multi-stage extensional unroofing in the Rila Mountains (SW Bulgaria)     

Christian Tueckmantel  Silke Schmidt  Markus Neisen  Neven Georgiev  Thorsten J. Nagel  Nikolaus Froitzheim 《Swiss Journal of Geoscience》2008,101(1):295-310

The Rhodope Metamorphic Province represents the core of an Alpine orogen affected by strong syn- and postorogenic extension. We report evidence for multiple phases of extensional unroofing from the western border of the Rila Mountains in the lower Rila valley, SW Bulgaria. The most prominent structure is the Rila-Pastra Normal Fault (RPNF), a major extensional fault and shear zone of Eocene to Early Oligocene age. The fault zone includes, from base to top, mylonites, ultramylonites and cataclasites, indicating deformation under progressively decreasing temperature, from amphibolite-facies to low-temperature brittle deformation. It strikes E–W with a top-to-the-N-to NW-directed sense of shear. Basement rocks in the hanging wall and footwall both display amphibolite-facies conditions. The foliation of the hanging-wall gneisses, however, is discordantly cut by the fault, while the foliation of the footwall gneisses is seen to curve into parallelism with the fault when approaching it. Two ductile splays of the RPNF occur in the footwall, which are subparallel to the foliation of the surrounding gneisses and merge laterally into the mylonites of the main fault zone. The concordance between the foliation in the footwall and the RPNF suggests that deformation and cooling in the footwall occurred simultaneously with extensional shearing, while the hanging-wall gneisses had already been exhumed previously. The RPNF is associated with thick deposits of an Early Oligocene, syntectonic breccia on top of its hanging wall. Integrating our results with previous studies, we distinguish the following stages of extensional faulting: (1) Late Cretaceous NW–SE extension (Gabrov Dol Detachment), exhumation of the present day hanging wall of the RPNF; (2) Eocene to Early Oligocene NW–SE to N–S extension (RPNF); (3) Miocene to Pliocene E–W extension (Western Border Fault), formation of the Djerman Graben; (4) Holocene to recent N–S to NW–SE extension (Stob Fault), reactivating the SW part of the Western Border Fault.  相似文献   

Geostandards and Geoanalytical Research Bibliographic Review 2007     

Klaus Peter Jochum  Stefanie M. Brueckner  Uwe Nohl  Brigitte Stoll  Ulrike Weis 《Geostandards and Geoanalytical Research》2008,32(4):509-514

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Biodegradation of the Antituberculosis Drug Isoniazid in the Aquatic Environment          下载免费PDF全文

Samuel Sasu  Jörg Metzger  Martin Kranert  Klaus Kümmerer 《洁净——土壤、空气、水》2015,43(2):166-172

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On the thick-disc exoplanet host subgiant HD 155358     

Klaus Fuhrmann  Jan Bernkopf † 《Monthly notices of the Royal Astronomical Society》2008,384(4):1563-1566

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On the dynamical origin of the ICM metallicity evolution     

Sofia A. Cora  Luca Tornatore  Paolo Tozzi  Klaus Dolag 《Monthly notices of the Royal Astronomical Society》2008,386(1):96-104

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Numerical simulation of a permittivity probe for measuring the electric properties of planetary regolith and application to the near‐surface region of asteroids and comets     

Klaus SPITZER  Frank SOHL  Martin PANZNER 《Meteoritics & planetary science》2008,43(6):997-1007

Abstract— We present a numerical simulation technique for the retrieval of the electric properties relative permittivity and conductivity of planetary, asteroid, and cometary regolith. Our simulation techniques aim at accompanying hardware development and conducting virtual experiments, e.g., to assess the response of arbitrary heterogeneous conductivity and permittivity distributions or to scrutinize possibilities for spatial reconstruction methods using inverse schemes. In a first step, we have developed a finite element simulation code on the basis of unstructured, adaptive triangular grids for arbitrary two‐dimensional axisymmetric distributions of conductivity and permittivity. The code is able to take into account the spatial geometry of the probe and allows for possible inductive effects. In previous studies, the non‐inductive approach has been used to convert potential and phase data into apparent material properties. By our simulations, we have shown that this approach is valid for the frequency range from 10² Hz to 10⁷ Hz and electric conductivities of 10^?8 S/m that are typical for the near‐surface region of asteroids and comets composed of chondritic materials and/or frozen volatiles such as H₂O and CO₂ ice. We prove the accuracy of our code to be better than 10%, using mixed types of boundary conditions and present a simulated vertical log through a horizontally stratified subsurface layer as a representative example of a heterogeneous distribution of the electrical properties. Resolution studies for the given electrode separation reveal that the material parameters of layers having thicknesses of less than about half the electrode spread are not reconstructible if only apparent quantities are considered. Therefore, spatial distributions of the complex sensitivity are presented having in mind a future data inversion concept that will permit the multi‐dimensional reconstruction of material parameters in heterogeneous environments.  相似文献   

Satellitenbild und Meereiserkundung     

Klaus Strübing 《Ocean Dynamics》1970,23(5):193-213

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Improved prediction of vegetation composition in NW European softwater lakes by combining location,water and sediment chemistry     

Cristina?PulidoEmail author  Kaj?Sand-Jensen  Esther?C.?H.?E.?T.?Lucassen  Jan?G.?M.?Roelofs  Klaus?P.?Brodersen  Ole?Pedersen 《Aquatic Sciences - Research Across Boundaries》2012,74(2):351-360

Isoetids, as indicators of near-pristine softwater lakes, have a high priority in national and international (European Water Directive Framework) assessments of ecological lake quality. Our main goal was to identify the most important environmental factors that influence the composition of plant communities and specifically determine the presence and abundance of the isoetid Lobelia dortmanna in NW European softwater lakes. Geographical position and composition of surface water, porewater, sediment and plant communities were examined in 39 lakes in four regions (The Netherlands, Denmark, West Norway and East Norway) distributed over a 1,200-km long distance. We confirmed that lake location was accompanied by significant changes in environmental variables between NW European lakes. Lake location was the single most important determinant of vegetation composition and it had significant individual contributions independent of the coupling to environmental variables. This influence of location was supported by a significant decline of community similarity with geographical distance between pairs of lakes at regional, inter-regional and international scales. Combining the geographical position with environmental variables for surface water, porewater and sediment significantly improved prediction of vegetation composition. Specifically, the combination of latitude, surface water alkalinity, porewater phosphate and redox potential offered the highest correlation (BIO ENV correlation 0.66) to vegetation composition. This complex analysis can also account for high sediment variability in the littoral zone of individual lakes, by using site-specific physico-chemical sediment factors, and offer better predictions of vegetation composition when lake water chemistry is relatively homogeneous among lakes within regions.  相似文献